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2 edition of Thermal and mechanical properties of crystalline polyesters poly(ethylene terephthalate) and poly(butylene terephthalate) found in the catalog.

Thermal and mechanical properties of crystalline polyesters poly(ethylene terephthalate) and poly(butylene terephthalate)

Salem Ismail Khalil

Thermal and mechanical properties of crystalline polyesters poly(ethylene terephthalate) and poly(butylene terephthalate)

by Salem Ismail Khalil

  • 309 Want to read
  • 34 Currently reading

Published by University of Birmingham in Birmingham .
Written in English


Edition Notes

Thesis (Ph.D.) - University of Birmingham, Dept of Chemistry.

Statementby Salem Ismail Khalil.
ID Numbers
Open LibraryOL14832909M

  Polyamide (nylon) has excellent mechanical and thermal properties, good chemical resistance and low permeability to gases, but it is known to be resistant to degradation in the natural environment. The poor biodegradability of nylon in comparison with aliphatic polyesters is probably due to its strong interchain interactions caused by the. Offers coverage of all known commodity, transitional, engineering, high-temperature and high-performance thermoplastics, and analyzes emerging developments in the creation of new thermoplastics. The text examines: important issues in the field for each substance discussed, including history, development and commercialization; polymer formation mechanisms and process technologies; the 4/5(2).

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The group of Synthetic Polymers: Structure and radable Polymers (PSEP) belongs to the Universitat Politècnica de Catalunya (UPC) and is a part of the Consolidated Research Group (SGR) of Química team has a well defined and recognized research experience on synthetic polymers and is constituted by specialists on polymer synthesis; structural. A series of main-chain thermotropic liquid crystalline polyesters were synthesized by polycondensation from mesogenic dial such as 4,4′-bis(6-hydroxyhexyloxy)biphenyl (BHHBP) and various diacids with different substituents such as succinic acid (no side group), 2-methylsuccinic acid (aliphatic side group) and 2-phenylsuccinic acid (aromatic side group), named poly(4,4′-bis(6 Cited by:


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Thermal and mechanical properties of crystalline polyesters poly(ethylene terephthalate) and poly(butylene terephthalate) by Salem Ismail Khalil Download PDF EPUB FB2

Crystalline solid Solid crystalline state Temperature Figure A Melting point and glass transition temperature of polymer. TABLE A Glass Transition Temperatures of Some Polymers Polymer T g (∘C) Polytetrafluoroethylene −97 Polypropylene(isotactic) + Polystyrene + Poly(methylmethacrylate)(atactic) + Nylon6,6 +57 Polyethylene.

Thermal and mechanical properties as well as thermal and chemical stability are discussed with reference to the polyester structure.

Compounding, processing, recycling and applications of. In the case of commercial crystalline plastics wider differences are to be noted. Many polyethylenes have a yield strength below 14 MPa while polyamides may have a value of 83 MPa. In these polymers the intermolecular attraction, the molar mass and the type and amount of crystalline structure all influence the mechanical properties.

DensityCited by: 2. Stephen Z.D. Cheng, Shi Jin, in Handbook of Thermal Analysis and Calorimetry, 1 INTRODUCTION. Crystalline polymers constitute a class of important engineering plastic materials in industrial applications and human daily lives.

Some of the largest quantities produced each year in polymer industries are polyethylene and copolymers, polypropylene, polyesters and nylons. Polyesters occupy an important place in the group of polymers as engineering materials to be used in electrotechnology and electronics.

These polymers are characterized by excellent electro-insulating properties, showing mechanical strength, thermal resistance, and easiness in processing at the same time. The chapter presents the behavior analysis of the following polyesters in electric field Author: Wieslawa Urbaniak-Domagala.

Constrained amorphous interphase and mechanical properties of bio- based polyesters Abstract: Bio-based polymers belonging to the polyesters group, as poly(L-lactic acid) and poly(3- hydroxybutyrate), are semi-crystalline materials, whose properties must be explained by taking into account the contribution of both the crystalline and the.

Effects of the mixing ratio of poly(DL-lactide) (PDLLA) and poly (ε-caprolactone) (PCL) on the thermal and mechanical properties and morphologies of the solution-cast blends were investigated by.

Dicarboxylic acids, glycols, diamines, epoxy resins, phenolics, etc., have significant uses in a variety of thermoplastics and thermosets. Cyclic imino ethers may be used to react with the functionalities on the aforesaid starting compounds, providing practical paths to a host of improved performance materials.

Crystallization of polymers is a process associated with partial alignment of their molecular chains. These chains fold together and form ordered regions called lamellae, which compose larger spheroidal structures named spherulites.

Polymers can crystallize upon cooling from melting, mechanical stretching or solvent evaporation. Crystallization affects optical, mechanical, thermal and chemical. Poly (cyclohexanedimethanol cyclohexanedicarboxlic acid) (PCC), a fairly newly synthesized polyester, has been studied.

Having a good experience of increasing both thermal stability and service temperature when applied to typical polymers, poly (tetramethylene glycol) (PTMG) was selected as a softening agent that was randomly copolymerized into the PCC : Osamu Matsumoto, Atsushi Hotta.

Provides an overview of the family of polyester polymers which comprise an important group of plastics that span the range of commodity polymers to engineering resins. It describes the preparation, properties and applications of polyesters. Readers will also find details on polyester-based elastomers, biodegradable aliphatic polyester, liquid crystal polyesters and unsaturated polyesters for.

change caused by heat.”1 Thermal degradation is “a process whereby the action of heat or elevated tempera-ture on a material, product, or assembly causes a loss of physical, mechanical, or electrical properties.”1 In terms of fire, the important change is thermal decomposition, whereby the chemical decomposition of a solid material.

Liquid crystallinity in polymers may occur either by dissolving a polymer in a solvent (lyotropic liquid-crystal polymers) or by heating a polymer above its glass or melting transition point (thermotropic liquid-crystal polymers).Liquid-crystal polymers are present in melted/liquid or solid form.

In solid form the main example of lyotropic LCPs is the commercial aramid known as Kevlar. The glass-transition and crystalline-melting temperatures can be determined by a wide range of techniques including measurement of volume (dilatometry), specific heat (calorimetry), and mechanical properties, particularly modulus (e.g., dynamic mechanical analysis), as discussed in Chapter 4.

Polyhydroxyalkanoates are a wide family of polyesters, obtained by different bacteria cultivated under stressful conditions, with properties quite similar to conventional plastics [1,2,3].The commercially marketed PHBV copolymers have good mechanical properties [] and good resistance to solubility in water [].PHB and PHBV are also highly biodegradable and biocompatible [6,7,8].Cited by: 1.

2 PHB/PEN/PET Mechanical Blends. The Liquid Crystalline Phase. Thermal behavior. Mechanical properties. Transesterification. 3 Effect of a catalyst on the compatibility of LCP/PEN Blends. Mechanical property improvement. Dispersion of LCP in PEN. Heterogeneity of the : $ Apart from PEV, other vanillic polymers have been synthesized, as the aromatic units tend to increase the mechanical properties and the T g of the resulting polymers [27,28,29,30,31].

Finally, vanillic acid has also been incorporated in thermotropic liquid crystalline polyesters [32,33,34,35,36].Author: Alexandra Zamboulis, Lazaros Papadopoulos, Zoi Terzopoulou, Dimitrios N.

Bikiaris, Dimitra Patsiaour. Structure property relationships (Roger, ) The nature- aliphatic or aromatic- of the bivalent - R 1 - and - R 2 - radicals in polyester chains (Scheme 1) exerts a prefound influence on the properties of polyesters and define four main classes of linear polyesters.

Aliphatic polyesters are low melting (40 - 80 °C) semicrystalline polymers or viscous fluids and present inferior Cited by: 3. Ali F, Chang Y-W, Kang SC, Yoon JY () Thermal, mechanical and rheological properties of poly (lactic acid)/epoxidized soybean oil blends.

Polym Bull 62(1)– doi: /s CrossRef Google ScholarCited by: 8. Title of Dissertation: Thermotropic Liquid Crystalline Polyesters based on the monomer of Poly(ethylene terephthalate) Satish Baliga, Doctor of Engineering Science, Dissertation directed by: Dr.

Wing T. Wong Assistant Professor Department of Chemical Engineering, Chemistry and Environmental ScienceAuthor: Satish Baliga. Plummer CJG, Wu Y, Davies P, Zulle B, Demarmels A, Kausch HH (a) The short- and long-term mechanical properties of filled and unfilled thermotropic liquid crystalline polymer injection moldings.

J Appl Polym Sci – CrossRef Google ScholarCited by: 1. In the past few years, thermotropic liquid crystalline polymers (TLCPs) have been attracting much attention due to their unique properties such as good thermal stability, high strength and modulus, excellent chemical resistance (), (), (), (), (), ().For TLCPs, they consist of two basic units, rigid and flexible units, and the liquid crystalline features arise from rigidity present in the Cited by: 5.

Thermal, mechanical and wettability properties of some branched polyetherurethane elastomers The influence of polymerization temperature on structure and properties of polyaniline One pot synthesis and characterization of industrially important graft copolymer (GOH-g-ACM) by using peroxymonosulphate/ mercaptosuccinic acid redox pairCited by: 8.